镍基耐蚀Hastelloy G3合金的组织特征及热力学计算

利用Thermo-Calc软件对镍基耐蚀Hastelloy G3合金进行了热力学计算，系统研究了成分对平衡相析出的影响规律，并通过SEM和TEM对合金时效处理后的析出相进行了观察。结果表明，合金析出的平衡相主要为σ相、μ相、M6C和M23C6；Cr、Mo含量主要影响σ相和μ相析出量及开始析出温度；而C元素显著影响碳化物M6C和M23C6的析出行为；进一步通过试验研究了时效过程中析出相的析出规律。     

High temperature deformation behavior and microstructure evolution of wrought nickel-based superalloy GH4037 in solid and semi-solid states

Cylindrical samples of Ni-based GH4037 alloy were compressed at solid temperatures (1200, 1250 and 1300 °C) and semi-solid temperatures (1340, 1350, 1360, 1370 and 1380 °C) with different strain rates of 0.01, 0.1 and 1 s⁻¹. High temperature deformation behavior and microstructure evolution of GH4037 alloy were investigated. The results indicated that flow stress decreased rapidly at semi-solid temperatures compared to that at solid temperatures. Besides, the flow stress continued to increase after reaching the initial peak stress at semi-solid temperatures when the strain rate was 1 s⁻¹. With increasing the deformation temperature, the size of initial solid grains and recrystallized grains increased. At semi-solid temperatures, the grains were equiaxed, and liquid phase existed at the grain boundaries and inside the grains. Discontinuous dynamic recrystallization (DDRX) characterized by grain boundary bulging was the main nucleation mechanism for GH4037 alloy.     

Effect of metallurgical evolution during post-weld aging treatment on localised corrosion of resistance spot welding joints of A286 superalloy

The combined effect of resistance spot welding and precipitation hardening on the localised corrosion of A286 superalloy is studied. The specimens tested by double loop electrochemical potentiokinetic reactivation were welded in the solution treated condition, and then subjected to different precipitation hardening treatments. For both base metal and weld nugget, the maximum localised corrosion is reached when η phase is clearly observable. The fact that the localised corrosion resistance of weld nugget is different from that shown by base metal may be explained by the segregation of Ni and Ti towards the interdendritic region of weld nugget (studied by using scanning electron microscope/energy dispersive X-ray analysis).     

热等静压处理对K439B高温合金显微组织的影响

对K439B合金进行了1165 ℃/150 MPa,4 h热等静压处理,采用光学显微镜和扫描电镜对比研究了铸态和热等静压态K439B合金的显微组织。结果表明:铸态K439B合金存在0.25%的显微疏松,热等静压后显微疏松基本消除(0.013%)。与铸态相比,经过热等静压处理后合金中的γ/γ′共晶组织体积分数和尺寸减小,各元素分布更加均匀,凝固偏析系数均更接近1。铸态K439B合金枝晶干处γ′相尺寸和体积分数分别是116.9 nm和17.8%,枝晶间部位γ′相尺寸和体积分数分别为244.4 nm和24.9%。热等静压后合金枝晶干部位的γ′相尺寸及体积分数分别为148.0 nm和17.5%,枝晶间部位γ′相尺寸和体积分数分别为159.1 nm和22.8%。热等静压处理使合金枝晶干、枝晶间部位的γ′相尺寸、体积分数和形貌接近,同时γ′相分布变得均匀。     

Microstructural evolution and defect formation in a powder metallurgy nickel-based superalloy processed by selective laser melting

In this study,the selective laser melting(SLM)technology has been employed to manufacture a nickelbased superalloy which was conventionally prepared through powder metallurgy(PM)route.The microstructural features and defects were systematically investigated both prior to and after heat treatment and compared with the PM counterpart.Both solidification cracking and liquation cracking were observed in the SLM specimen in which the grain misorientation and low melting point(γ+γ')eutectic played a vital role in their formation mechanism.Columnar grains oriented along building direction were ubiquitous,corresponding to strong<001>fiber texture.Solidification cell structures and melt pools are pervasive and noγ'precipitates were detected at about 10 nm scale before heat treatment.After supersolvus solution and two-step aging treatments,high volume fractionγ'precipitates emerged and their sizes and morphologies were comparable to those in PM alloy.<001>texture is relieved and columnar grains tend to become more equiaxed due to static recrystallization process and grain boundary migration events.Significant annealing twins formed in SLM alloy and are clarified as a consequence of recrystallization.Our results provide fundamental understandings for the SLM PM nickel-based superalloy both before and after heat treatment and demonstrate the potential to fabricate this group of alloys using SLM technology.     

毫米波波束管理的设计与研究

毫米波是第五代移动通信系统的重要通信技术,因其频谱特性可以利用大带宽承载大量信息,有效提升系统的吞吐量。高频段毫米波传输具有高损耗性,且受环境影响较大,为了支持非视距和移动性,必须支持准确且实时的波束跟踪以确保信号传输质量。波束管理的目的是使得基站与终端之间发送与接收波束对准以提高链路的性能。文中根据3GPP协议规范设计了波束管理方案,包括以下几方面的内容:波束扫描、波束测量、波束上报、波束指示、波束失败恢复。     

重组大肠杆菌表达17β-羟基类固醇脱氢酶全细胞催化合成宝丹酮的研究

宝丹酮作为一种重要的蛋白同化雄性激素类固醇，具有提升肌肉质量和耐力的功能。宝丹酮的传统合成方法是以1,4-雄烯二酮（ADD）为底物通过化学法合成，但过程复杂、污染严重。17β-羟基类固醇脱氢酶（17β-HSD）可催化甾体化合物C-17位点的氧化还原反应，实现ADD和宝丹酮的相互转化。本研究通过基因序列同源性分析，筛选到6种不同来源的17β-HSD基因并对其在大肠杆菌中进行异源表达。利用不同重组菌转化ADD合成宝丹酮，结果表明重组菌BL21/pET28a-HSDPy的ADD转化率最高，因此选择BL21/pET28a-HSDPy进行进一步研究。鉴定了重组菌的酶学性质并优化其全细胞转化条件。结果表明在生物量为36 g·L^-1、底物浓度为5.40 g·L^-1条件下，经过两次补料，获得了3.66 g·L^-1宝丹酮，比优化前提高了4.1倍。而且在生物转化过程中未检测到副产物。为生物合成宝丹酮提供了可能。     

二甲双胍联合糖皮质激素治疗伴糖耐量异常的系统性红斑狼疮患者的临床研究

目的: 探究二甲双胍联合糖皮质激素治疗伴糖耐量异常(IGT)的系统性红斑狼疮(SLE)患者的临床疗效及对胰岛功能、Th17/Treg细胞失衡的影响。方法: 本院84例伴IGT的SLE患者随机分为联用组和对照组各42例,均给予生活、饮食指导,对照组给予糖皮质激素治疗,联用组联合二甲双胍治疗,1个月后观察疗效,并评估胰岛功能和Th17/Treg细胞失衡情况。结果: 联用组总有效率明显高于对照组(90.48% vs. 71.43%,P<0.05),SLE活动指数评分为(2.6±0.3)分,红细胞沉降率(ESR)为(18±4)mm/h,显著低于对照组的(3.9±0.8)分、(23±4)mm/h(P<0.05)。治疗后联用组空腹血糖(FBG)、空腹胰岛素(Fins)、稳态模型-胰岛素抵抗指数(HOMA-IR)、胰岛β功能细胞指数(HOMA-β)显著改善(P<0.05),且与对照组相比差异有统计学意义(P<0.05);联用组正常糖耐量(NGT)占比明显高于对照组(73.81% vs. 30.95%,P<0.05)。治疗后联用组Th17、Treg细胞比例为(6.2±0.9)个/μL、(31±7)个/μL,Th17/Treg为(0.20±0.05),与对照组的(7.4±1.3)个/μL、(28±7)个/μL、(0.26±0.06)相比有统计学差异(P<0.05)。治疗后SLE活动指数评分与HOMA-IR、HOMA-β及Th17细胞、Treg细胞、Th17/Treg明显相关(P<0.05),且HOMA-IR、HOMA-β与Th17细胞、Treg细胞、Th17/Treg也明显相关(P<0.05)。2组不良反应均轻微,发生率无统计学差异(P>0.05)。结论: 二甲双胍联合糖皮质激素治疗伴IGT的SLE患者疗效显著,可控制疾病活动性,降低血糖水平、改善胰岛功能及纠正Th17/Treg细胞失衡,且安全性高。     

WIDESTARII卫星移动通信方案研究

WIDESTAR II系统为了更好的满足用户需求,在WIDESTAR系统的基础之上对移动终端、基站设备以及核心网节点进行了再次开发,从而实现了更高的传输速率以及与IMS或其他通用IP技术的灵活兼容。本文中,将首先对WIDESTAR II系统进行简要的介绍与分析,然后,对此系统所采用频谱效率提高方法、IP兼容技术以及时延降低策略等卫星移动通信机制进行研究与验证。     

Microstructure and magnetostrictive performance of NbC-doped<100>oriented Fe-Ga alloys

The<100>oriented Fe83Ga17 alloy rods with various NbC contents less than 1at%were prepared by the directional solidification method at a growth rate of 720 mm?h?1. Low NbC-content was found to affect t...